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'Unzipped' carbon nanotubes could help energize fuel cells and batteries, Stanford scientists say
Date:5/27/2012

contributes virtually nothing, except to promote active sites made entirely of nitrogen."

To address the controversy, the Stanford team enlisted scientists at Oak Ridge National Laboratory to conduct atomic-scale imaging and spectroscopy analysis of the nanotubes. The results showed clear, visual evidence of iron and nitrogen atoms in close proximity.

"For the first time, we were able to image individual atoms on this kind of catalyst," Dai said. "All of the images showed iron and nitrogen close together, suggesting that the two elements are bonded. This kind of imaging is possible, because the graphene pieces are just one-atom thick."

Dai noted that the iron impurities, which enhanced catalytic activity, actually came from metal seeds that were used to make the nanotubes and were not intentionally added by the scientists. The discovery of these accidental yet invaluable bits of iron offered the researchers an important lesson. "We learned that metal impurities in nanotubes must not be ignored," Dai said.


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Contact: Mark Shwartz
mshwartz@stanford.edu
650-723-9296
Stanford University
Source:Eurekalert  

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'Unzipped' carbon nanotubes could help energize fuel cells and batteries, Stanford scientists say
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