Navigation Links
Oxidation mechanisms at gold nanoclusters unraveled

Researchers believe that the puzzle of catalytic gold is now partially solved. Gold can catalyse an oxidation reaction by first oxidising itself. New research evidence on gold-oxide phase at room temperature and atmospheric pressure help us to finally understand the oxidation mechanisms of catalytic gold nanoclusters in these conditions.

"This is vital if we want to design oxidation catalysts that could use ambient oxygen in the reaction process. Catalysts that function at low temperatures are significant in terms of energy efficiency in the future," says Academy Research Fellow Karoliina Honkala at the Nanoscience Centre (NSC) of the University of Jyvskyl.

The researchers at the NSC show new evidence from computational studies that supported nanometer-sized gold clusters can completely break the O-O bond by formation of a novel one-dimensional gold-oxide phase at the boundary of the cluster. This mechanism is predicted to dominate at ambient conditions of one atmospheric pressure and room temperature.

The study was published in September in Angewandte Chemie, the leading international journal in chemistry. The study is part of Karoliina Honkala's Academy of Finland Academy Researcher project and it was conducted in cooperation with Professor Hannu Hkkinen. The computational work was facilitated by extensive resources from the Finnish IT Center for Science, CSC.

In the study, researchers exposed the monolayer-thick gold clusters to a variable number of oxygen molecules. It was found that even one gold cluster can effectively adsorb multiple oxygen molecules at the boundaries of the cluster, simultaneously weakening (stretching) the O-O bond by transferring electrons to the oxygen molecules. Taking into account the effects of temperature and ambient pressure, the calculations predicted that the oxygen molecules will completely dissociate and the oxygen and gold atoms will form one-dimensional alternating chains at the cluster boundary (see Figure). The oxygen atoms in these chains are negatively and the gold atoms positively charged, creating a system that is reminiscent to a one-dimensional gold-oxide chain. These chains are expected to be the highly catalytically active part towards conversion of carbon monoxide to carbon dioxide at room temperature.

Researchers Pentti Frondelius, Hannu Hkkinen and Karoliina Honkala have studied monolayer-thick gold clusters with 10-20 atoms, supported by thin magnesium oxide films that were grown on silver metal. These systems can be prepared experimentally, and last year the Jyvskyl group published a joint study with Professor Hans-Joachim Freund from the Fritz-Haber Institute in Berlin to characterize atomic and electronic structures of gold clusters in such systems (see

Intensive experimental work since the early 1980s has indicated that gold nanoparticles exhibit unexpected catalytic activity towards many industrially important chemical reactions that involve activation of atomic bonds inside oxygen or hydrocarbon molecules. Room-temperature formation of carbon dioxide (CO2) from carbon monoxide (CO) and oxygen molecule (O2) is one of the most extensively studied processes. A number of different factors have been suggested to contribute to the ability of gold particles to activate the O-O bond, which is considered to be the key reaction step.

"The study now published provides us with a new approach to the problem. The formation of gold oxide, that is, the oxidation of gold, is in contradiction with the known properties of macroscopic gold metal. On the nanometer scale, however, everything seems to be possible," Professor Hkkinen says.


Contact: Hannu Hkkinen
Academy of Finland

Related biology technology :

1. Titanium coating with protein flower bouquet nanoclusters strengthens implant attachment
2. Controlling the size of nanoclusters
3. Mysterious charge transport in self-assembled monolayer transistors unraveled
Post Your Comments:
Related Image:
Oxidation mechanisms at gold nanoclusters unraveled
(Date:11/25/2015)... , Nov. 25, 2015 /PRNewswire/ - Aeterna Zentaris ... that its business and prospects remain fundamentally strong ... Zoptrex™ (zoptarelin doxorubicin) recently received DSMB recommendation to ... completion following review of the final interim efficacy ... 2 Primary Endpoint in men with heavily pretreated ...
(Date:11/25/2015)... CA (PRWEB) , ... November 25, 2015 , ... ... genomics company uBiome, were featured on AngelList early in their initial angel funding ... an AngelList syndicate for individuals looking to make early stage investments in the ...
(Date:11/24/2015)... 2015 Halozyme Therapeutics, Inc. (NASDAQ: HALO ) will ... New York on Wednesday, December 2 at 9:30 a.m. ... and CEO, will provide a corporate overview. th ... at 1:00 p.m. ET/10:00 a.m. PT . Jim Mazzola ... a corporate overview. --> th Annual Oppenheimer Healthcare ...
(Date:11/24/2015)... , Nov. 24, 2015 /PRNewswire/ - Aeterna Zentaris ... of IIROC on behalf of the Toronto Stock Exchange, ... release there are no corporate developments that would cause ... --> --> About Aeterna ... . --> Aeterna Zentaris is a ...
Breaking Biology Technology:
(Date:11/18/2015)... Nov. 18, 2015  As new scientific discoveries deepen ... and other healthcare providers face challenges in better using ... patients. In addition, as more children continue to survive ... adulthood and old age. John M. Maris, ... Hospital of Philadelphia (CHOP) . --> ...
(Date:11/17/2015)... , Nov. 17, 2015 Pressure BioSciences, Inc. ... the development and sale of broadly enabling, pressure cycling ... sciences industry, today announced it has received gross proceeds ... million Private Placement (the "Offering"), increasing the total amount ... or more additional closings are expected in the near ...
(Date:11/11/2015)... MedNet Solutions , an innovative SaaS-based eClinical technology company that ... announce that it will be a Sponsor of the ... held November 17-19 in Hamburg , Germany.  ... iMedNet , MedNet,s easy-to-use, proven and affordable eClinical ... able to deliver time and cost savings of up to ...
Breaking Biology News(10 mins):